| Autor: |
Julian Spils, Thomas Wirth, Boris J Nachtsheim |
| Rok vydání: |
2022 |
| Předmět: |
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| DOI: |
10.26434/chemrxiv-2022-9q4px |
| Popis: |
We describe a multi-step continuous-flow procedure for the generation of six-membered diaryliodonium salts. The accompanying scalability and atom economy are significant improvements to existing batch methods. Benzyl acetates are submitted to this two-step procedure as highly available and cheap starting materials. An acid-catalyzed Friedel–Crafts alkylation followed by an anodic oxidative cyclization yielded a defined set of cyclic iodonium salts in a highly substrate-dependent yield. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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