Hydrosoluble phosphonic acid functionalized poly(2‐ethyl‐2‐oxazoline) chelating polymers for the sorption of metallic cations
| Autor: | Vincent Lapinte, Titouan Montheil, Belkacem Tarek Benkhaled, Sophie Monge |
|---|---|
| Přispěvatelé: | Institut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier (ICGM ICMMM), Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM)-Centre National de la Recherche Scientifique (CNRS)-Université de Montpellier (UM)-Université Montpellier 1 (UM1)-Université Montpellier 2 - Sciences et Techniques (UM2)-Institut de Chimie du CNRS (INC) |
| Jazyk: | angličtina |
| Rok vydání: | 2020 |
| Předmět: |
phosphonic acid
Polymers and Plastics 02 engineering and technology 010402 general chemistry 01 natural sciences Hydrolysis chemistry.chemical_compound Polymer chemistry Materials Chemistry Copolymer [CHIM.COOR]Chemical Sciences/Coordination chemistry Physical and Theoretical Chemistry chemistry.chemical_classification Aqueous solution sorption Chemistry Ethyleneimine Sorption Polymer water treatment 021001 nanoscience & nanotechnology Phosphonate 6. Clean water 0104 chemical sciences polyoxazoline [CHIM.POLY]Chemical Sciences/Polymers Michael reaction metallic cations 0210 nano-technology |
| Zdroj: | Journal of Polymer Science Journal of Polymer Science, John Wiley & Sons, 2020, 58 (20), pp.2875-2886. ⟨10.1002/pol.20200487⟩ |
| ISSN: | 0022-3832 1542-6238 |
| Popis: | International audience; In the present contribution, the synthesis of well‐defined water‐soluble phosphonic‐acid based poly(2‐ethyl‐2‐oxazoline) and the preliminary study of their sorption properties were reported. For such purpose, poly(2‐ethyl‐2‐oxazoline) (POx) was first prepared. Then, controlled hydrolysis allowed the obtaining of statistical poly(2‐ethyl‐2‐oxazoline)‐stat‐poly(ethyleneimine) (POx‐st‐PEI) with 20% of ethyleneimine units, which allowed maintaining water solubility of the copolymers. The latter were successfully functionalized with either dimethyl(acryloyloxymethyl) phosphonate (APC1) or diethyl‐2‐(acrylamido)ethylphosphonate (DAAmEP) using Michael reaction. Phosphonated esters were hydrolyzed to produce phosphonic acid groups, thus, leading to hPOx‐st‐PEI‐APC1 and hPOx‐st‐PEI‐DAAmEP copolymers. Finally, functionalized statistical copolymers were successfully used for the sorption of divalent or trivalent metallic cations. The reported work aims at reporting the synthesis of original polyoxazoline materials functionalized with phosphonic acid groups that could be further employed for water treatment in polymer enhanced ultrafiltration processes. |
| Databáze: | OpenAIRE |
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