Investigating biomass burning aerosol morphology using a laser imaging nephelometer
| Autor: | Nicholas L. Wagner, Joshua P. Schwarz, Katherine M. Manfred, Rebecca A. Washenfelder, A. Franchin, Gabriela Adler, Frank Erdesz, Robert J. Yokelson, Daniel M. Murphy, Vanessa Selimovic, Kara D. Lamb, Caroline C. Womack |
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| Rok vydání: | 2018 |
| Předmět: |
Atmospheric Science
education.field_of_study 010504 meteorology & atmospheric sciences Nephelometer Spectrometer business.industry Scattering Mie scattering Population 010501 environmental sciences 01 natural sciences lcsh:QC1-999 Aerosol lcsh:Chemistry Optics lcsh:QD1-999 Radiative transfer Environmental science business education Particle counter lcsh:Physics Physics::Atmospheric and Oceanic Physics 0105 earth and related environmental sciences Remote sensing |
| Zdroj: | Atmospheric Chemistry and Physics, Vol 18, Pp 1879-1894 (2018) |
| ISSN: | 1680-7324 |
| DOI: | 10.5194/acp-18-1879-2018 |
| Popis: | Particle morphology is an important parameter affecting aerosol optical properties that are relevant to climate and air quality, yet it is poorly constrained due to sparse in situ measurements. Biomass burning is a large source of aerosol that generates particles with different morphologies. Quantifying the optical contributions of non-spherical aerosol populations is critical for accurate radiative transfer models, and for correctly interpreting remote sensing data. We deployed a laser imaging nephelometer at the Missoula Fire Sciences Laboratory to sample biomass burning aerosol from controlled fires during the FIREX intensive laboratory study. The laser imaging nephelometer measures the unpolarized scattering phase function of an aerosol ensemble using diode lasers at 375 and 405 nm. Scattered light from the bulk aerosol in the instrument is imaged onto a charge-coupled device (CCD) using a wide-angle field-of-view lens, which allows for measurements at 4–175∘ scattering angle with ∼ 0.5∘ angular resolution. Along with a suite of other instruments, the laser imaging nephelometer sampled fresh smoke emissions both directly and after removal of volatile components with a thermodenuder at 250 ∘C. The total integrated aerosol scattering signal agreed with both a cavity ring-down photoacoustic spectrometer system and a traditional integrating nephelometer within instrumental uncertainties. We compare the measured scattering phase functions at 405 nm to theoretical models for spherical (Mie) and fractal (Rayleigh–Debye–Gans) particle morphologies based on the size distribution reported by an optical particle counter. Results from representative fires demonstrate that particle morphology can vary dramatically for different fuel types. In some cases, the measured phase function cannot be described using Mie theory. This study demonstrates the capabilities of the laser imaging nephelometer instrument to provide realtime, in situ information about dominant particle morphology, which is vital for understanding remote sensing data and accurately describing the aerosol population in radiative transfer calculations. |
| Databáze: | OpenAIRE |
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