Hydrolysis of Element (White) Phosphorus under the Action of Heterometallic Cubane-Type Cluster {Mo3PdS4}
| Autor: | A. V. Sukhov, Dmitry G. Yakhvarov, Artem L. Gushchin, Maxim N. Sokolov, Aidar M. Kuchkaev, Oleg G. Sinyashin, Khasan R. Khayarov, Airat M. Kuchkaev, Nikita Y. Shmelev, Vasily M. Babaev |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2021 |
| Předmět: |
Pharmaceutical Science
chemistry.chemical_element 010402 general chemistry 01 natural sciences Article Analytical Chemistry lcsh:QD241-441 chemistry.chemical_compound Bipyridine molybdenum lcsh:Organic chemistry Drug Discovery Cluster (physics) Organometallic Compounds Molecule Physical and Theoretical Chemistry Phosphorous acid white phosphorus 010405 organic chemistry White Phosphorus Hydrolysis Organic Chemistry Phosphorus phosphine palladium 0104 chemical sciences Crystallography chemistry Chemistry (miscellaneous) Molybdenum Molecular Medicine heterometallic cubane-type clusters phosphorous acid Phosphine Palladium |
| Zdroj: | Molecules Volume 26 Issue 3 Molecules, Vol 26, Iss 538, p 538 (2021) |
| ISSN: | 1420-3049 |
| DOI: | 10.3390/molecules26030538 |
| Popis: | Reaction of heterometallic cubane-type cluster complexes&mdash [Mo3{Pd(dba)}S4Cl3(dbbpy)3]PF6, [Mo3{Pd(tu)}S4Cl3(dbbpy)3]Cl and [Mo3{Pd(dba)}S4(acac)3(py)3]PF6, where dba&mdash dibenzylideneacetone, dbbpy&mdash 4,4&prime di-tert-butyl-2,2&prime bipyridine, tu&mdash thiourea, acac&mdash acetylacetonate, py&mdash pyridine, with white phosphorus (P4) in the presence of water leads to the formation of phosphorous acid H3PO3 as the major product. The crucial role of the Pd atom in the cluster core {Mo3PdS4} has been established in the hydrolytic activation of P4 molecule. The main intermediate of the process, the cluster complex [Mo3{PdP(OH)3}S4Cl3(dbbpy)3]+ with coordinated P(OH)3 molecule and phosphine PH3, have been detected by 31P NMR spectroscopy in the reaction mixture. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
| Nepřihlášeným uživatelům se plný text nezobrazuje | K zobrazení výsledku je třeba se přihlásit. |