HClO4–SiO2 catalyzed glycosylation using sugar trichloroacetimidates as glycosyl donors

Autor:	Robert J. Linhardt, Yuguo Du, Yuxia Hua, Shuihong Cheng, Guohua Wei
Rok vydání:	2006
Předmět:	Glycosylation Low toxicity Chemistry Organic Chemistry General Medicine Key features Biochemistry Combinatorial chemistry Catalysis chemistry.chemical_compound Yield (chemistry) Drug Discovery Organic chemistry Glycosyl Perchloric acid Sugar
Zdroj:	Tetrahedron Letters. 47:307-310
ISSN:	0040-4039
Popis:	Silica-supported perchloric acid (HClO4-SiO2) has been used as an efficient promoter,, as a replacement of TMSOTf, in various glycosylation reactions using sugar trichloroacetimidates as glycosyl donors. Operational simplicity, economic considerations, high yield, short reaction time and low toxicity were the key features associated with this protocol. (c) 2005 Elsevier Ltd. All rights reserved.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::1ac1b158bdb14b94c7c8c28f4f5a4fa4 https://doi.org/10.1016/j.tetlet.2005.11.025 Zobrazit plný text záznamu Full Text from ScienceDirect