Chiral phosphine oxide aziridinyl phosphonate as a Lewis base catalyst for enantioselective allylsilane addition to aldehydes

Autor:	Özdemir Dogan, M. Ali Tecimer, Adnan Bulut
Přispěvatelé:	Kırıkkale Üniversitesi
Jazyk:	angličtina
Rok vydání:	2015
Předmět:	Phosphine oxide Organic Chemistry Enantioselective synthesis Phosphonate Catalysis Inorganic Chemistry chemistry.chemical_compound chemistry Yield (chemistry) Organic chemistry Lewis acids and bases Methanol Physical and Theoretical Chemistry
Popis:	WOS: 000360774600014 A series of chiral Lewis bases, phosphine oxide ferrocenyl aziridinyl methanol 1-4, phosphinyl aziridinyl phosphonates 5 and 6, and phosphine oxide aziridinyl phosphonates 7 and 8 were screened for allylsilane additions to aldehydes. Among the Lewis bases, 8 was found to catalyze the reaction by forming the product in up to 94% yield and with 77% ee. (C) 2015 Elsevier Ltd. All rights reserved. Scientific and Technical Research Council of Turkey (TUBITAK)Turkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [TBAG-110T073]; Middle East Technical University Research FoundationMiddle East Technical University We thank the Scientific and Technical Research Council of Turkey (TUBITAK, Grant No. TBAG-110T073) and the Middle East Technical University Research Foundation for the financial support.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::167855cabea3aa107e162653da056b20 https://hdl.handle.net/20.500.12587/6060 Zobrazit plný text záznamu