Nanoarchitectures for Mesoporous Metals
| Autor: | Yusuke Yamauchi, Hongjing Wang, Kevin C.-W. Wu, Jung Ho Kim, Hamed Ataee-Esfahani, Cuiling Li, Bo Jiang, Victor Malgras |
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| Rok vydání: | 2015 |
| Předmět: |
Materials science
Mechanical Engineering Nanoparticle Nanotechnology 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences Mesoporous organosilica Template Mechanics of Materials Lyotropic Nanoarchitectonics General Materials Science Self-assembly 0210 nano-technology Porosity Mesoporous material |
| Zdroj: | Advanced Materials. 28:993-1010 |
| ISSN: | 0935-9648 |
| DOI: | 10.1002/adma.201502593 |
| Popis: | The field of mesoporous metal nanoarchitectonics offers several advantages which cannot be found elsewhere. These materials have been showcasing impressive enhancements of their electrochemical properties for further implementation, compared to their micro- and macroporous counterparts. Since the last few decades, various methods have been developed to achieve narrow pore size distribution with a tunable porosity and particle morphology. While hard templates offer a reliable and intuitive approach to synthesize mesoporous metals, the complexity of the technique and the use of harmful chemicals pushed several research groups to focus in other directions. For example, soft templates (e.g., lyotropic crystals, micelles assemblies) and solution phase methods (requiring to control reduction reactions) offer more and more possibilities in terms of available compositions and morphologies. Indeed, various metal (Pt, Pd, Au, Ru, etc.) can now be synthesized as dendritic, core@shell, hollow or polyhedral nanoparticles, with single- or multicomponents, alloyed or not, with unprecedented electrochemical activity. |
| Databáze: | OpenAIRE |
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