Isolation and characterization of major diterpenes from C. canephora roasted coffee oil
| Autor: | Luciano Navarini, Elena Guercia, Federico Berti, Cristina Forzato, Nicola Demitri |
|---|---|
| Přispěvatelé: | Guercia, Elena, Berti, Federico, Navarini, Luciano, Demitri, Nicola, Forzato, Cristina |
| Rok vydání: | 2016 |
| Předmět: |
Canephora
Cafestol 01 natural sciences Catalysis Inorganic Chemistry chemistry.chemical_compound terpenoids medicine Organic chemistry Physical and Theoretical Chemistry Anomalous scattering biology 010405 organic chemistry Chemistry 010401 analytical chemistry Organic Chemistry Absolute configuration Carbon-13 NMR biology.organism_classification Terpenoid 0104 chemical sciences absolute configuration cafestol cristal structure terpenoid Derivative (chemistry) medicine.drug |
| Zdroj: | Tetrahedron: Asymmetry. 27:649-656 |
| ISSN: | 0957-4166 |
| Popis: | A simple laboratory procedure for the isolation of pure cafestol and 16-O-methylcafestol together with β-sitosterol from coffee is disclosed. Cafestol and 16-O-methylcafestol have been exhaustively characterized through 1D and 2D 1H, 13C NMR, CD and X-ray diffraction. For the first time, the molecular structure of cafestol is reported and the assignment of the absolute configuration is unequivocally given by exploiting anomalous scattering of a brominated derivative. |
| Databáze: | OpenAIRE |
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