Physico-chemical Properties, Biological and Environmental Impact of Nb-saponites Catalysts for the Oxidative Degradation of Chemical Warfare Agents
| Autor: | Tatyana V. Kramar, Matteo Guidotti, M. V. Taran, Daniele Costenaro, C. Bisio, Sergey L. Safronyuk, Fabio Carniato, Andrey M. Katsev, Mykola F. Starodub |
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| Rok vydání: | 2017 |
| Předmět: |
Chemical Warfare Agents
Oxidative degradation 010405 organic chemistry Niobium Biological and Environmental impact Blistering agents General Chemistry 010402 general chemistry 01 natural sciences Catalysis 0104 chemical sciences Environmental chemistry Environmental science Environmental impact assessment Saponite Clay |
| Zdroj: | ChemistrySelect 2 (2017): 1812–1819. doi:10.1002/slct.201700042 info:cnr-pdr/source/autori:Costenaro, Daniele; Bisio, Chiara; Carniato, Fabio; Safronyuk, Sergey L.; Kramar, Tatyana V.; Taran, Marina V.; Starodub, Mykola F.; Katsev, Andrey M.; Guidotti, Matteo/titolo:Physico-chemical Properties, Biological and Environmental Impact of Nb-saponites Catalysts for the Oxidative Degradation of Chemical Warfare Agents/doi:10.1002%2Fslct.201700042/rivista:ChemistrySelect/anno:2017/pagina_da:1812/pagina_a:1819/intervallo_pagine:1812–1819/volume:2 |
| ISSN: | 2365-6549 |
| Popis: | Niobium-containing saponite clays are active catalysts, under mild ambient conditions and in the presence of aqueous hydrogen peroxide, in the oxidative abatement of sulfurcontaining blister chemical warfare agent simulants, such as (2chloroethyl) ethyl sulfide. Over a Nb-saponite solid, a complete, selective and safe abatement of the chemical agent was attained within 8 h. The biological and environmental impact of the Nb-containing nanostructured clays used as decontamination solids was assessed by specific rapid biotoxicity tests on bioluminescent bacteria and vegetable plants. No negative impact on the strain of luminescent bacteria was evidenced in terms of acute and chronic toxicity. No adverse effects have been observed on vegetable plants in terms of germination, vigour and induction of chlorophyll fluorescence either. |
| Databáze: | OpenAIRE |
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