Mechanical Reinforcement And Memory Effect Of Strain-Induced Soft Segment Crystals In Thermoplastic Polyurethane-Urea Elastomers
| Autor: | Iskender Yilgor, Grégory Stoclet, Jean-Francois Tahon, Yusuf Z. Menceloğlu, Adrien Demongeot, Emel Yilgor, Nicolas Candau, Oguzhan Oguz |
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| Přispěvatelé: | Universitat Politècnica de Catalunya. Departament de Ciència i Enginyeria de Materials |
| Rok vydání: | 2021 |
| Předmět: |
Strain induced crystallization
Materials science Elastòmers Polymers and Plastics 02 engineering and technology 010402 general chemistry Elastomer Enginyeria dels materials [Àrees temàtiques de la UPC] Memory effect 01 natural sciences law.invention Thermoplastic polyurethane law Phase (matter) Ultimate tensile strength X-rays Materials Chemistry Thermoplastics Mechanical reinforcement Composite material Crystallization Thermoplastic polyurethane-urea Organic Chemistry Termoplàstics 021001 nanoscience & nanotechnology 0104 chemical sciences Elastomers Hardening (metallurgy) Crystallite Deformation (engineering) 0210 nano-technology |
| Popis: | An amorphous poly(urethane-urea) copolymer composed of 70 wt% poly(ethylene oxide) (PEO) soft segments (SS) (Mw = 2000 g mol-1) and 30 wt% cycloaliphatic hard segments (HS) was subjected to in-situ X-Rays during tensile deformation. Mechanical hardening at room temperature was attributed to strain induced crystallization (SIC) of the PEO SS through the multiplication of aligned crystallites. The permanent nature of these crystals after stress removal indicates a certain mechanical stability, which we related here to the concomitant effect of superstraining of the SS crystallites and the HS reorganization upon deformation. This is in marked contrast to previous studies which reported the crystalline phase to be temporary upon unloading. A manifestation of such enhanced stability is the memory effect evidenced by an increased crystallizability of PEO segments during incremental cyclic loading. These results offer a way to (i) tune the mechanical properties of TPUs via the formation of mechanically stable pre-oriented SS crystals and to (ii) tune the thermally/water activated shape memory properties of TPUs (shape fixity, kinetics of shape memory recovery). |
| Databáze: | OpenAIRE |
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