Post-synthetic modification mechanism for 1D spin crossover coordination polymers
| Autor: | Alejandro Enríquez-Cabrera, Livia Getzner, Lionel Salmon, Lucie Routaboul, Azzedine Bousseksou |
|---|---|
| Přispěvatelé: | Laboratoire de chimie de coordination (LCC), Institut de Chimie de Toulouse (ICT), Institut de Recherche pour le Développement (IRD)-Université Toulouse III - Paul Sabatier (UT3), Université de Toulouse (UT)-Université de Toulouse (UT)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Institut National Polytechnique (Toulouse) (Toulouse INP), Université de Toulouse (UT)-Institut de Recherche pour le Développement (IRD)-Université Toulouse III - Paul Sabatier (UT3), Université de Toulouse (UT)-Centre National de la Recherche Scientifique (CNRS), ANR-19-CE09-0008,NAGAM,Actionnement nanomoléculaire pour une nouvelle génération de muscles artificiels(2019) |
| Jazyk: | angličtina |
| Rok vydání: | 2022 |
| Předmět: | |
| Zdroj: | New Journal of Chemistry New Journal of Chemistry, 2022, 46 (46), pp.22004-22012. ⟨10.1039/D2NJ04015H⟩ |
| ISSN: | 1144-0546 1369-9261 |
| DOI: | 10.1039/D2NJ04015H⟩ |
| Popis: | International audience; In this work we present a comprehensive study of the influence of the solvent on the post-synthetic modification (PSM) on the [Fe(NH2trz)3](NO3) spin crossover (SCO) complex with p-anisaldehyde. We demonstrate that the use of a suitable solvent such as ethanol results in a complete PSM, where the final crystalline material exhibits a gradual conversion just below room temperature. In the other hand, when an unsuitable solvent such as toluene or 1-octanol is used, either no reaction or very long reaction time is needed, leading to undesired Fe(III) species. Transmission electronic microscopy analyses show that the complete PSM reaction carried out on nanoparticles of the same complex, changes drastically the size and morphology of the particles. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|