Mixed micelles of benzyldimethyltetradecylammonium chloride with tetradecyltrimethylammonium and tetradecyltriphenylphosphonium bromides: a head group contribution

Autor: Shweta Sachar, Gurinder Kaur, Ishpinder Kaur, Rohit Sood, Kulbir Singh, Mandeep Singh Bakshi, Jasmeet Singh, Kanwar Jit Singh
Rok vydání: 2004
Předmět:
Zdroj: Journal of colloid and interface science. 271(1)
ISSN: 0021-9797
Popis: Mixed micelle formation by tetradecyltrimethylammonium (TTAB) and tetradecyltriphenylphosphonium bromides (TTPB) with benzyldimethyltetradecylammonium chloride (BTDACl) was studied with the help of conductivity and Kraft point measurements. The BTDACl + TTAB mixtures showed synergistic interactions whereas those of BTDACl + TTPB indicated weak antagonistic behavior. From Kraft temperature measurements, the enthalpy of fusion ( H 1 0 ) from solid hydrated BTDACl to the liquid state in the presence of TTAB or TTPB was computed. It was found that Δ H 1 0 was much more positive for BTDACl + TTPB than for BTDACl + TTAB mixtures.
Databáze: OpenAIRE