Optimized Production of Multilayered Monodisperse Polymer Nanoparticles
| Autor: | M. Abderrazak Latifi, Fernand Pla, Brahim Benyahia, Christian Fonteix |
|---|---|
| Přispěvatelé: | Laboratoire Réactions et Génie des Procédés (LRGP), Centre National de la Recherche Scientifique (CNRS)-Université de Lorraine (UL), Equipe de Recherche sur les Processus Innovatifs (ERPI), Université de Lorraine (UL), Gernaey, KV and Huusom, JK and Gani, Université de Lorraine (UL)-Centre National de la Recherche Scientifique (CNRS) |
| Jazyk: | angličtina |
| Rok vydání: | 2015 |
| Předmět: |
chemistry.chemical_classification
Materials science Butyl acrylate Dispersity Nanoparticle Chain transfer 02 engineering and technology Polymer 021001 nanoscience & nanotechnology Styrene chemistry.chemical_compound Monomer 020401 chemical engineering chemistry Chemical engineering Polymer chemistry [CHIM]Chemical Sciences 0204 chemical engineering 0210 nano-technology Glass transition |
| Zdroj: | 12TH INTERNATIONAL SYMPOSIUM ON PROCESS SYSTEMS ENGINEERING (PSE) AND 25TH EUROPEAN SYMPOSIUM ON COMPUTER AIDED PROCESS ENGINEERING (ESCAPE), PT A 12TH INTERNATIONAL SYMPOSIUM ON PROCESS SYSTEMS ENGINEERING (PSE) AND 25TH EUROPEAN SYMPOSIUM ON COMPUTER AIDED PROCESS ENGINEERING (ESCAPE), PT A, 2015, Copenhague, Denmark. pp.863-868 |
| Popis: | 12th International Symposium on Process Systems Engineering (PSE) / 25th European Symposium on Computer Aided Process Engineering (ESCAPE), Copenhagen, DENMARK, MAY 31-JUN 04, 2015; International audience; A dynamic optimization frame work is used to produce in a controlled way multilayered latex nanoparticles. The key feature of the method is to track a glass transition temperature profile, which is designed to produce polymer layers with the targeted properties. Several constraints are considered to achieve better control and produce nanoparticles with a specified particle diameter and layers' thicknesses. To enhance the control of the different layers, two separate monomer feeds are considered under starving conditions throughout the fed-batch stages. The emulsion copolymerization of styrene and butyl acrylate in the presence of n-C12 mercaptan, as chain transfer agent (CTA), is illustrated here as a case study. The optimal feed profiles of the pre-emulsioned monomers are obtained using a genetic algorithm. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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