Determination of the magnetostrictive atomic environments in FeCoB alloys

Autor: L. M. Alvarez-Prado, Sakura Pascarelli, J. Díaz, C. Quirós, Rocío Ranchal, C. Aroca, M. P. Ruffoni
Přispěvatelé: Ministerio de Ciencia e Innovación (España)
Rok vydání: 2012
Předmět:
Zdroj: Digital.CSIC. Repositorio Institucional del CSIC
instname
Physical Review B, ISSN 1098-0121, 2012-04, Vol. 85, No. 13
Archivo Digital UPM
ISSN: 1550-235X
1098-0121
DOI: 10.1103/physrevb.85.134437
Popis: PACS number(s): 61.05.cj, 61.43.Dq, 75.80.+q, 75.50.Kj.-- et al.
The atomic environments of Fe and Co involved in the magnetostriction effect in FeCoB alloys have been identified by differential extended x-ray fine structure (DiffEXAFS) spectroscopy. The study, done in amorphous and polycrystalline FeCoB films, demonstrates that the alloys are heterogeneous and that boron plays a crucial role in the origin of their magnetostrictive properties. The analysis of DiffEXAFS in the polycrystalline and amorphous alloys indicates that boron activates magnetostriction when entering as an impurity into octahedral interstitial sites of the Fe bcc lattice, causing its tetragonal distortion. Magnetostriction would be explained then by the relative change in volume when the tetragonal axis of the site is reoriented under an externally applied magnetic field. The experiment demonstrates the extreme sensitivity of DiffEXAFS to characterize magnetostrictive environments that are undetectable in their related EXAFS spectra. © 2012 American Physical Society.
Work supported by Spanish MICINN (Grant Nos. FIS2008-06249 and HP2008-0032).
Databáze: OpenAIRE