Assessing the Roles of the Constituents of Ionic Liquids in Dynamic Solvation: Comparison of an Ionic Liquid in Micellar and Bulk Form
| Autor: | Mintu Halder, Daniel W. Armstrong, Jacob W. Petrich, Prasun Mukherjee, Jeffrey A. Crank |
|---|---|
| Rok vydání: | 2006 |
| Předmět: |
Imidazoles
Solvation Ionic Liquids Water Heterocyclic Compounds 4 or More Rings Micelle Chemical kinetics Solvent chemistry.chemical_compound Models Chemical chemistry Coumarins Computational chemistry Ionic liquid Solvents Moiety Organic chemistry Molecule Physical and Theoretical Chemistry Micelles |
| Zdroj: | The Journal of Physical Chemistry A. 110:10725-10730 |
| ISSN: | 1520-5215 1089-5639 |
| Popis: | Dynamic solvation of the dye, coumarin 153, is compared in an ionic liquid that forms micelles in water against the bulk solvent. This provides the unprecedented opportunity of investigating the behavior of the ionic liquid in two globally different configurations. It is proposed that the imidazolium moiety is in both cases responsible for the majority of the solvation, which manifests itself in the first 100 ps. Exploiting the use of ionic liquids capable of accommodating specific structures thus provides a deeper insight into how solutes interact with these fascinating and interesting solvents (at least those that are imidazolium based) that are gaining ever increasing interest in the scientific community. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|