Reversible structural isomerisation in rare thioether complexes of cobalt(ii)—effects of ligand architecture

Autor:	Joanna M. Manning, Nikolaos Tsoureas, John Evans, Gillian Reid, William Levason, Michael Webster
Rok vydání:	2007
Předmět:	Ligand Stereochemistry chemistry.chemical_element Crystal structure Inorganic Chemistry chemistry.chemical_compound Crystallography Monomer chemistry Octahedron Thioether Structural isomer Cobalt Isomerization
Zdroj:	Dalton Trans.. :1986-1988
ISSN:	1477-9234 1477-9226
DOI:	10.1039/b702792c
Popis:	Rare examples of (high spin) Co(II) complexes with geometrically constrained tetrathioether ligands exhibit a very unusual structural isomerism, switching reversibly between tetrahedral monomers in solution and octahedral chain polymers in the solid; the crystal structures of one polymeric species and a tetrahedral monomer model compound are described.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::09f88a900f22881874278ade063a1a31 https://doi.org/10.1039/b702792c Zobrazit plný text záznamu