Organocatalytic asymmetric transferhydrogenation of beta-nitroacrylates: accessing beta2-amino acids
| Autor: | Xu Cheng, Nolwenn J. A. Martin, Benjamin List |
|---|---|
| Rok vydání: | 2008 |
| Předmět: |
chemistry.chemical_classification
Molecular Structure Chemistry Enantioselective synthesis Stereoisomerism General Chemistry Optically active Nitro Compounds Biochemistry Catalysis Amino acid chemistry.chemical_compound Colloid and Surface Chemistry Thiourea Acrylates Molecule Organic chemistry Hydrogenation Amino Acids Conjugate |
| Zdroj: | Journal of the American Chemical Society. 130(42) |
| ISSN: | 1520-5126 |
| Popis: | We describe a highly efficient and enantioselective Hantzsch ester mediated conjugate reduction of beta-nitroacrylates that is catalyzed by a Jacobsen thiourea catalyst as a key step in a new route to optically active beta2-amino acids. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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