Spectroscopy, Interactions, and Level Splittings in Au Nanoparticles

Autor: Michael Tinkham, Dragomir Davidovic
Rok vydání: 1999
Předmět:
Zdroj: Physical Review Letters. 83:1644-1647
ISSN: 1079-7114
0031-9007
Popis: We have measured the electronic energy spectra of nm-scale Au particles using a new tunneling spectroscopy configuration. The particle diameters ranged from 5nm to 9nm, and at low energies the spectrum is discrete, as expected by the electron-in-a-box model. The density of tunneling resonances increases rapidly with energy, and at higher energies the resonances overlap forming broad resonances. Near the Thouless energy, the broad resonances merge into a continuum. The tunneling resonances display Zeeman splitting in a magnetic field. Surprisingly, the g-factors (~0.3) of energy levels in Au nano-particles are much smaller than the g-factor (2.1) in bulk gold.
Databáze: OpenAIRE