Synthesis of new pyrrole–pyridine-based ligands using an in situ Suzuki coupling method
| Autor: | H.-H. Johannes, Björn Wiegmann, Steffen Schaumburg, Wolfgang Kowalsky, Matthias Böttger, Peter G. Jones |
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| Rok vydání: | 2012 |
| Předmět: |
boronic acids
pyrrole-pyridine Hydrogen bond Organic Chemistry Combinatorial chemistry Full Research Paper lcsh:QD241-441 Chemistry chemistry.chemical_compound Bipyridine lcsh:Organic chemistry chemistry Suzuki reaction Pyridine Polymer chemistry Imidazole Molecule lcsh:Q Suzuki coupling complex chemistry lcsh:Science Boronic acid in situ generation Pyrrole |
| Zdroj: | Beilstein Journal of Organic Chemistry, Vol 8, Iss 1, Pp 1037-1047 (2012) Beilstein Journal of Organic Chemistry |
| ISSN: | 1860-5397 |
| Popis: | The compounds 6-(pyrrol-2-yl)-2,2‘-bipyridine, 2-(pyrrol-2-yl)-1,10-phenanthroline and 2-(2-(N-methylbenz[d,e]imidazole)-6-(pyrrol-2-yl)-pyridine were synthesized by using an in situ generated boronic acid for the Suzuki coupling. Crystals of the products could be grown and exhibited interesting structures by X-ray analysis, one of them showing a chain-like network with the adjacent molecules linked to each other via intermolecular N–H…N hydrogen bonds. |
| Databáze: | OpenAIRE |
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