Elastic charge density representation of the interaction via the nematic director field
| Autor: | V. O. Uzunova, V. M. Pergamenshchik |
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| Rok vydání: | 2007 |
| Předmět: |
Models
Molecular Physics Field (physics) Static Electricity Biophysics Scalar (physics) Charge density Charge (physics) Surfaces and Interfaces General Chemistry Electrostatics Liquid Crystals Condensed Matter::Soft Condensed Matter Dipole Classical mechanics Models Chemical Liquid crystal Elastic Modulus Quantum mechanics Computer Simulation General Materials Science Multipole expansion Biotechnology |
| Zdroj: | The European Physical Journal E. 23:161-174 |
| ISSN: | 1292-895X 1292-8941 |
| DOI: | 10.1140/epje/i2006-10169-x |
| Popis: | The interaction between particle-like sources of the nematic director distortions (e.g., colloids, point defects, macromolecules in nematic emulsions) allows for a useful analogy with the electrostatic multipole interaction between charged bodies. In this paper we develop this analogy to the level corresponding to the charge density and consider the general status of the pairwise approach to the nematic emulsions with finite-size colloids. It is shown that the elastic analog of the surface electric charge density is represented by the two transverse director components on the surface imposing the director distortions. The elastic multipoles of a particle are expressed as integrals over the charge density distribution on this surface. Because of the difference between the scalar electrostatics and vector nematostatics, the number of elastic multipoles of each order is doubled compared to that in the electrostatics: there are two elastic charges, two vectors of dipole moments, two quadrupolar tensors, and so on. The two-component elastic charge is expressed via the vector of external mechanical torque applied on the particle. As a result, the elastic Coulomb-like coupling between two particles is found to be proportional to the scalar product of the two external torques and does not directly depend on the particles' form and anchoring. The real-space Green function method is used to develop the pairwise approach to nematic emulsions and determine its form and restrictions. The pairwise potentials are obtained in the familiar form, but, in contrast to the electrostatics, they describe the interaction between pairs (dyads) of the elastic multipole moments. The multipole moments are shown to be uniquely determined by the single-particle director field, unperturbed by other particles. The pairwise approximation is applicable only in the leading order in the small ratio particle size-to-interparticle distance as the next order contains irreducible three-body terms. |
| Databáze: | OpenAIRE |
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