Hydrophobic interactions of alkanols. A calorimetric study in water at 298.15 K

Autor:	Vittorio Elia, Ciro Cascella, Giuseppina Castronuovo, Roberto Sartorio, Silvana Wurzburger
Přispěvatelé:	C., Cascella, Castronuovo, Giuseppina, V., Elia, R., Sartorio, S., Wurzburger
Rok vydání:	1990
Předmět:	Hydrophobic effect chemistry.chemical_classification chemistry.chemical_compound Aqueous solution Chemistry Enthalpy Diol Structural isomer Thermodynamics Molecule Physical and Theoretical Chemistry Alkyl Dilution
Zdroj:	Journal of the Chemical Society, Faraday Transactions. 86:85
ISSN:	1364-5455 0956-5000
DOI:	10.1039/ft9908600085
Popis:	Enthalpies of dilution in water of binary aqueous solutions of n-diols of increasing alkyl chain length are performed using a flow microcalorimeter. The pairwise enthalpic coefficients of these hydrophobic solutes depend mainly on the mutual positions of the -OH groups in the molecule. A rationalization of the excess enthalpies of positional isomers is attempted.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::027fb77a847666861afd6c2059f16d1a https://doi.org/10.1039/ft9908600085 Zobrazit plný text záznamu