Dearomatizing and Derivatizing a Mesityl Group on Boron by One-Pot Photoisomerization and [4+2] Diels-Alder Addition

Autor:	Xiang Wang, Billy Deng, Suning Wang
Rok vydání:	2019
Předmět:	Photoisomerization 010405 organic chemistry Aryl Organic Chemistry chemistry.chemical_element General Chemistry Conjugated system 010402 general chemistry Ring (chemistry) 01 natural sciences Borirane Medicinal chemistry Catalysis 3. Good health 0104 chemical sciences chemistry.chemical_compound chemistry Group (periodic table) Chelation Boron
Zdroj:	Chemistry (Weinheim an der Bergstrasse, Germany). 25(64)
ISSN:	1521-3765
Popis:	Boron compounds having a conjugated chelate backbone (N,C-chelate or C,C-chelate) and two mesityl substituents on boron have been found to undergo a facile one-pot transformation/reaction with dienophiles, which leads to the dearomatization of one mesityl ring and its [4+2] Diels-Alder addition with the dienophile. Photochemical activation is the key in this transformation of the aryl ring.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::01f837b7cfc426d599b9764607917b13 https://pubmed.ncbi.nlm.nih.gov/31486136 Zobrazit plný text záznamu Plný text