Bis{μ-2-[(pyridin-2-yl)iminomethyl]phenolato}bis[(2-formylphenolato)copper(II)]
| Autor: | Jacqueline M. Cole, Sven O. Sylvester, Hui-Chang Chang, Tze-Chia Lin, Paul G. Waddell |
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| Jazyk: | angličtina |
| Rok vydání: | 2011 |
| Předmět: |
Metal-Organic Papers
Dimer chemistry.chemical_element 02 engineering and technology General Chemistry Meth 021001 nanoscience & nanotechnology 010403 inorganic & nuclear chemistry Condensed Matter Physics 01 natural sciences Medicinal chemistry Copper 0104 chemical sciences chemistry.chemical_compound Monomer chemistry General Materials Science 0210 nano-technology |
| Zdroj: | Acta Crystallographica Section E: Structure Reports |
| ISSN: | 1600-5368 |
| Popis: | The asymmetric unit of the title compound, [Cu(2)(C(12)H(9)N(2)O)(2)(C(7)H(5)O(2))(2)], contains two independent (2-formyl-phen-olato){2-[(pyridin-2-yl)imino-meth-yl]phenolato}copper(II) mol-ecules that form pseudocentrosymmetric dimers via inter-actions between the Cu and pyridyl N atoms of independent monomers. The square-planar geometry of the Cu atoms in the monomer thus becomes square-based pyramidal in the dimer. The crystal studied was an inversion twin, with unequal populations of 0.353 (17) and 0.647 (17). |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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