THE OBSERVATION OF PSEUDOROTATING LITHIUM AND POTASSIUM CLUSTERS LI-5 AND K-7 IN AN ADAMANTANE MATRIX
| Autor: | Peter P. Edwards, James A. Howard, H. A. Joly, Richard J. Singer, R. Jones, David E. Logan |
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| Jazyk: | angličtina |
| Rok vydání: | 2016 |
| Předmět: |
chemistry.chemical_classification
Chemistry Annealing (metallurgy) Potassium Adamantane Inorganic chemistry General Physics and Astronomy chemistry.chemical_element Alkali metal law.invention Crystallography chemistry.chemical_compound Hydrocarbon law Physical and Theoretical Chemistry Electron paramagnetic resonance |
| Popis: | The pseudorotating clusters, Li5 and K7, have been identified in an adamantane matrix by EPR spectroscopy. These new clusters were synthesised by depositing the parent alkali metal atoms at 77 K in the hydrocarbon matrix followed by careful annealing to temperatures above 200 K. |
| Databáze: | OpenAIRE |
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