Synthesis, Characterization, and Crystal Structure of a Chiral Platinum(II) Complex with 2-(4-Methoxy-Phenyl)-Imidazo[4, 5-f][l,10]-Phenanthroline Binding Interaction with DNA
| Autor: | Yan Yang, Zhi-Hui Luo, Wei-Jiang Liang, Xu-Jian Luo, S. L. Wang, Rong-Jun Liu, J. M. Xu |
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| Rok vydání: | 2017 |
| Předmět: |
010405 organic chemistry
Chemistry General Chemical Engineering Phenanthroline chemistry.chemical_element General Chemistry Crystal structure 010402 general chemistry 01 natural sciences Fluorescence Hydrothermal circulation 0104 chemical sciences Crystallography chemistry.chemical_compound Platinum complex Platinum DNA |
| Zdroj: | Russian Journal of Coordination Chemistry. 43:679-684 |
| ISSN: | 1608-3318 1070-3284 |
| DOI: | 10.1134/s1070328417100050 |
| Popis: | A new platinum(II) complex of [Pt(Chda)(4-MOPIP)]2+2Cl– · H2O (I) (Chda = cyclohexanediamine; 4-MOPIP = (4-methoxy-phenyl)-imidazo[4,5-f][l,10]-phenanthroline) has been synthesized by hydrothermal methods and characterized by elemental analysis, IR, single-crystal X-ray diffraction (CIF file CCDC no. 1472980), UV-Vis and fluorescent spectrum. In complex I, the platinum adopts a four-coordinated square planar geometry. The DNA-binding interaction has been investigated. The complex can bind to DNA by intercalative mode, presenting the high DNA-binding affinity. |
| Databáze: | OpenAIRE |
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