Reactions of N-bromohexamethyldisilazane with triorganylsilanes

Autor:	D. V. Gendin, V. I. Rakhlin, T. F. Podgorbunskaya, M. G. Voronkov, Mirskov Rudolf G
Rok vydání:	2006
Předmět:	Reaction conditions chemistry.chemical_compound Cyclohexane chemistry Yield (chemistry) General Chemistry Irradiation Solvent effects Photochemistry Benzene Medicinal chemistry
Zdroj:	Russian Journal of General Chemistry. 76:1562-1563
ISSN:	1608-3350 1070-3632
DOI:	10.1134/s1070363206100094
Popis:	Reactions of N-bromohexamethyldisilazane (Me3Si)2NBr with Si-H compounds of the general formula RR′2SiH yield up to 90% of unsymmetrical disilazanes (Me3Si)2NSiRR′2 and bromotrimethylsilane. An unexpected solvent effect on the reaction conditions is revealed: In benzene the products are formed already on mixing, whereas in cyclohexane, under UV irradiation only.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ff3564bad1eb82080bc6db69e9bf76f3 https://doi.org/10.1134/s1070363206100094 Zobrazit plný text záznamu Plný text ve formátu PDF