Monoacrylated cyclodextrin via 'click' reaction and copolymerization with N-isopropylacrylamide: guest controlled solution properties

Autor:	Maricica Munteanu, Helmut Ritter, SooWhan Choi
Rok vydání:	2008
Předmět:	Acrylate Polymers and Plastics Chemistry Organic Chemistry Gel permeation chromatography chemistry.chemical_compound Monomer Dynamic light scattering Propargyl Polymer chemistry Materials Chemistry Copolymer Carboxylate Methyl methacrylate
Zdroj:	Journal of Polymer Research. 16:389-394
ISSN:	1572-8935 1022-9760
DOI:	10.1007/s10965-008-9240-0
Popis:	Mono-(1 H-1, 2, 3-triazol-4-yl) (methyl) 2-methylacryl-β-cyclodextrin (CD) 3 is synthesized by microwave assisted `click´ reaction of propargyl (meth) acrylate and mono-(6-azido-6-deoxy)-β-CD using Cu (I) catalysis. Free radical copolymerizations of monomer 3 with N-isopropylacrylamide 5 (NIPAAM) of different portions are carried out. The properties of polymers are characterized by use of gel permeation chromatography (GPC), dynamic light scattering (DLS) and turbidity measurements. The Lower Critical Solution Temperatures (LCSTs) of the copolymers with different portions of NIPAAM and influence of guest molecules addition by adamantly carboxylate and adamantly methyl methacrylate are evaluated.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::fe5b72da4c54b5bb2c09b7e68adebb06 https://doi.org/10.1007/s10965-008-9240-0 Zobrazit plný text záznamu Full text from SpringerLink