SYNTHESIS, CRYSTAL STRUCTURE, AND STABILITY OF N-LUPINYLPHTHALIMIDE CONFORMERS

Autor:	O. A. Nurkenov, K. M. Turdybekov, D. M. Turdybekov, Zh. S. Nurmaganbetov, S. D. Fazylov, A. S. Makhmutova, Zh. B. Satpaeva
Rok vydání:	2020
Předmět:	Materials science Solid-state physics Cyclohexane conformation Substituent Crystal structure Inorganic Chemistry Phthalimide chemistry.chemical_compound Crystallography chemistry Materials Chemistry Physical and Theoretical Chemistry Potassium phthalimide Conformational isomerism Single crystal
Zdroj:	Journal of Structural Chemistry. 61:1823-1826
ISSN:	1573-8779 0022-4766
DOI:	10.1134/s0022476620110153
Popis:	As a result of studying the interaction of chlorolupinine with potassium phthalimide, the optimal synthesis conditions for N-lupinylphthalimide by the Gabriel method are identified. The crystal structure of N-lupinylphthalimide is determined for the first time by single crystal XRD. The energy characteristics are calculated using the quantum chemical method. It is found that the conformer with the chair conformation of the cycles with the axial orientation of the phthalimide substituent is more stable than that with the equatorial orientation.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::fdbf252c31098815bfdeed7a02eb58fb https://doi.org/10.1134/s0022476620110153 Zobrazit plný text záznamu Plný text ve formátu PDF