Thermal stability and composition of products from thermal breakdown of additive ?ABES? as determined by pyrolytic gas chromatography
| Autor: | A. A. Fufaev, S. B. Borshchevskii, N. A. Kudryavtseva |
|---|---|
| Rok vydání: | 1975 |
| Předmět: |
chemistry.chemical_classification
Carbon disulfide Diethyl sulfide biology Sulfide Chemistry General Chemical Engineering Hydrogen sulfide Thermal decomposition Analytical chemistry Energy Engineering and Power Technology General Chemistry biology.organism_classification Abes chemistry.chemical_compound Fuel Technology Thermal stability Gas chromatography |
| Zdroj: | Chemistry and Technology of Fuels and Oils. 11:853-857 |
| ISSN: | 1573-8310 0009-3092 |
| DOI: | 10.1007/bf00731798 |
| Popis: | 1. Pyrolytic gas chromatography has been used to investigate the thermal stability and the composition of the degradation products obtained from the additive ABES. Components with boiling points up to about 300°C have been identified. Hydrogen sulfide is the main sulfur-containing product obtained by thermal breakdown of the additive. Present in very small amounts is ethyl mercaptan, with diethyl sulfide, carbon disulfide, and aromatic sulfur-containing compounds. 2. The initial decomposition temperature of the ABES additive has been determined at the break in the curves plotted for the relative amounts of hydrogen sulfide and ethylene as functions of the test temperature. These data are in agreement with those obtained by thermographic analysis. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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