Stereoselective synthesis of α-O-fucosylated serine, threonine, tyrosine and saccharides

Autor:	Rajendrakumar Reddy Gadikota, Srinivas Reddy Gurrala, Hari Babu Mereyala
Rok vydání:	1997
Předmět:	chemistry.chemical_classification Serine chemistry Stereochemistry Stereoselectivity Threonine Tyrosine Fucosylation Amino acid
Zdroj:	Journal of the Chemical Society, Perkin Transactions 1. :3179-3182
ISSN:	1364-5463 0300-922X
DOI:	10.1039/a704310d
Popis:	Stereoselective fucosylation of Boc-Ser/Thr/Tyr-OMe 2–4 and several saccharide alcohols 5–7 by coupling with 2-pyridyl tri-O-benzyl-1-thio-β-L-fucosyl donor 1b under iodomethane activation procedure results in the formation of α-linked fucosylated amino acid methyl ester building blocks 8–10 and α-linked fucosyl saccharides 11–13, respectively.
Databáze:	OpenAIRE
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