Interaction of certain?-dicarbonyl compounds with ethanedithiol and steric structure of the products formed

Autor:	G. N. Sergeeva, L. K. Yuldasheva, B. A. Arbuzov, E. N. Klimovitskii
Rok vydání:	1973
Předmět:	Steric effects chemistry.chemical_compound Phenylglyoxal chemistry Polymer chemistry Organic chemistry Glyoxal Ethanedithiol General Chemistry Benzil Diacetyl Dithiolane
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 22:2368-2371
ISSN:	1573-9171 0568-5230
Popis:	1. 1-Phenylpropane-1,2-dione gives a bis-1,3-dithiolane derivative in the reaction with 1,2-ethanedithiol, analogously to glyoxal and phenylglyoxaL Diacetyl and benzil give the corresponding monomercaptals. 2. 1-Phenylpropane-1,2-dione is reduced in the reaction with 1,2-ethanedithiol, forming 2-ethyl-2-phenyl-1, 3-dithiolane, 3. Bis-1,3-dithiolane derivatives of 1-phenylpropane-1, 2-dione, glyoxal, and phenylglyoxal exist in the gauche-form; 2-keto-l,3-dithiolanes from diacetyl and benzil have shielded structures with predominance of the S-conformer.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::faf852dce0be2a185e94a1a168ffae02 https://doi.org/10.1007/bf00926373 Zobrazit plný text záznamu Full text from SpringerLink