Experimental and theoretical investigation of the spectral and luminescent properties of some acridine compounds

Autor:	Lyibov G. Samsonova, V. G. Plotnikov, V. A. Sazhnikov, A. A. Khlebunov, N. I. Selivanov, M. V. Alfimov, V. Ya. Artyukhov, T. N. Kopylova, G. V. Maier
Rok vydání:	2009
Předmět:	Dipole chemistry.chemical_compound Reaction rate constant chemistry Excited state Acridine Protonation Physical and Theoretical Chemistry Absorption (chemistry) Internal conversion (chemistry) Photochemistry Luminescence
Zdroj:	High Energy Chemistry. 43:105-115
ISSN:	1608-3148 0018-1439
DOI:	10.1134/s0018143909020076
Popis:	Complex (experimental and quantum-chemical) investigation of the spectral and luminescent properties of acridine, 9-aminoacridine, 2,7-dimethyl-9-ditolylaminoacridine, and their protonated forms was performed. The electronic absorption and fluorescence spectra of the acridine dyes were studied at room temperature in ethanolic solutions at different pH values and in other solvents of different chemical nature and polarity. The energies of the excited states, the deactivation rate constants for the excited states, and the dipole moments are presented, which were obtained by calculations using the method of intermediate neglect of the differential overlap with special spectroscopic parameterization.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f9e2dc5014361d4d8f34f68294d095fd https://doi.org/10.1134/s0018143909020076 Zobrazit plný text záznamu Plný text ve formátu PDF