Heat release kinetics in the reaction of decane with nitric acid

Autor:	L. P. Andrienko, Yu. I. Rubtsov, E. Yu. Rubtsova, E. P. Kirpichev, A. I. Kazakov
Rok vydání:	1996
Předmět:	chemistry.chemical_compound chemistry Nitric acid Phase (matter) Nitration Kinetics Inorganic chemistry Nitrogen dioxide General Chemistry Decane Kinetic energy Catalysis
Zdroj:	Russian Chemical Bulletin. 45:1883-1888
ISSN:	1573-9171 1066-5285
DOI:	10.1007/bf01457769
Popis:	The kinetics of the reaction of decane with nitric acid (25.07–75.53 %) at 57.8 to 119 °C in an acid-decane-gas triphasic system was studied. The main contribution to the rate of heat release is made by the oxidation of decane with nitrogen dioxide in the organic phase proceedingvia the mechanism of a degenerate branched-chain reaction. Nitration plays the role of a chain termination reaction. The acid phase is the source of NO2, whose content increases with oxidation. The equilibrium of the nitrogen dioxide distribution in the triphasic system was analyzed. The kinetic law of the reaction, the dependences of the reaction constants of the initial and catalytic stages on temperature and the acid phase composition were determined. The results allow one to calculate the rate of heat release in the decane-HNO3 system under any conditions of the process.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f84e41c4e12579e80a22ce673f9794ab https://doi.org/10.1007/bf01457769 Zobrazit plný text záznamu Full text from SpringerLink