Gas-Phase Ethylene Polymerization by Single-Site Cr Centers in a Metal–Organic Framework
| Autor: | Robert J. Comito, Troy Van Voorhis, Chenyue Sun, Mircea Dincă, Jeffrey T. Miller, Zhenwei Wu, Yuriy Román-Leshkov, Guanghui Zhang, Hoyoung D. Park, Nathan D. Ricke |
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| Rok vydání: | 2020 |
| Předmět: |
Ethylene
Materials science 010405 organic chemistry General Chemistry Polyethylene 010402 general chemistry Heterogeneous catalysis 01 natural sciences Catalysis 0104 chemical sciences chemistry.chemical_compound chemistry Polymerization Single site Ethylene polymerization Polymer chemistry Metal-organic framework |
| Zdroj: | ACS Catalysis. 10:3864-3870 |
| ISSN: | 2155-5435 |
| DOI: | 10.1021/acscatal.9b03282 |
| Popis: | We report a systematic study on the gas-phase polymerization of ethylene by a metal–organic framework (MOF) catalyst. Cr3+-exchanged MFU-4l (Cr(III)-MFU-4l, MFU-4l = Zn5Cl4(BTDD)3, H2BTDD = bis(1H-... |
| Databáze: | OpenAIRE |
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