Gas-phase nucleophilic displacement reactions

Autor:	William N. Olmstead, John I. Brauman
Rok vydání:	1995
Předmět:	Displacement reactions Reaction rate constant Reaction sequence Nucleophile Chemistry Computational chemistry Nuclear Experiment Spectroscopy Ion cyclotron resonance Transition state Gas phase
Zdroj:	Journal of Mass Spectrometry. 30:1653-1662
ISSN:	1096-9888 1076-5174
Popis:	Displacement reactions of each of a variety of anionic nucleophiles reacting with each of a variety of neutrals have been studied by pulsed ion cyclotron resonance (ICR) spectroscopy. Rate constants for these reactions are interpreted in terms of a three-step reaction sequence. RRKM calculations are used to obtain information about the energy of transition states. The origin of the barrier to reaction in solution is discussed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f40ec6265a69452e310a699b14dafb88 https://doi.org/10.1002/jms.1190301204 Zobrazit plný text záznamu Plný text