Synthesis and electrochemical properties of peripheral, non-peripheral tetra [2-(3,5-diphenyl-1H-1,2,4-triazol-1-yl)ethoxy] substituted cobalt(II), manganese(III) phthalocyanines
Autor: | Ergun Gultekin, Zekeriya Bıyıklıoğlu, Turgut Keleş, Olcay Bekircan |
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Rok vydání: | 2019 |
Předmět: |
biology
010405 organic chemistry chemistry.chemical_element Manganese 010402 general chemistry Electrochemistry biology.organism_classification 01 natural sciences Medicinal chemistry 0104 chemical sciences Inorganic Chemistry Phthalonitrile chemistry.chemical_compound chemistry Materials Chemistry Alkoxy group Tetra Physical and Theoretical Chemistry Cyclic voltammetry Cobalt |
Zdroj: | Inorganica Chimica Acta. 487:201-207 |
ISSN: | 0020-1693 |
DOI: | 10.1016/j.ica.2018.12.010 |
Popis: | In this study, 4-[2-(3,5-diphenyl-1H-1,2,4-triazol-1-yl)ethoxy]phthalonitrile ET-CN, 3-[2-(3,5-diphenyl-1H-1,2,4-triazol-1-yl)ethoxy]phthalonitrile n-ET-CN and cobalt(II), manganese(III) phthalocyanines bearing [2-(3,5-diphenyl-1H-1,2,4-triazol-1-yl)ethoxy] group at peripheral, non-peripheral positions were synthesized for the first time. The new compounds have been characterized by FT-IR, NMR (only for ET-CN, n-ET-CN), mass and UV-Vis spectroscopy (except ET-CN, n-ET-CN) techniques. Electrochemistry of cobalt(II), manganese(III) phthalocyanines bearing [2-(3,5-diphenyl-1H-1,2,4-triazol-1-yl)ethoxy] group at peripheral, non-peripheral positions were examined by using cyclic voltammetry. |
Databáze: | OpenAIRE |
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