Cyclic carbonates synthesis from epoxides and CO2 over NIIC-10 metal-organic frameworks

Autor:	Anna A. Lysova, Grigoriy N. Bondarenko, Irina P. Beletskaya, Olga G. Ganina, Vladimir P. Fedin
Rok vydání:	2021
Předmět:	Process Chemistry and Technology DABCO Microporous material Catalysis chemistry.chemical_compound chemistry Carboxylation Bromide Chemical Engineering (miscellaneous) Organic chemistry Metal-organic framework Selectivity Waste Management and Disposal Octane
Zdroj:	Journal of CO2 Utilization. 53:101718
ISSN:	2212-9820
Popis:	A series of microporous metal-organic frameworks, NIIC-10, based on 2,5-thiophendicarboxylate (tdc2–), 1,4-diazabicyclo[2.2.2]octane (dabco), polyol ligands and Zn-ions were investigated in carboxylation of mono-, di and tri-substituted epoxides in the presence of tetrabuthylammonium bromide (TBAB). Reactions were carried out in solventless media under CO2 atmosphere and 80°C. All resulting mono- and disubstituted cyclic carbonates were obtained in good to excellent yields. Furthermore, the catalyst also showed good selectivity and recyclability for five cycles without a significant loss of activity.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f39a740ce186918e63280006c886ed07 https://doi.org/10.1016/j.jcou.2021.101718 Zobrazit plný text záznamu Full Text from ScienceDirect