An amino-decorated porous metal-organic framework for efficient C2 hydrocarbon/CH4 separation and high iodine adsorption
| Autor: | Junyu Lin, Ruidan Ma, Huadong Guo, Xianmin Guo, Shuang Liu, Ting Zhou, Zhiyong Guo, Fengyuan Wang |
|---|---|
| Rok vydání: | 2020 |
| Předmět: |
chemistry.chemical_classification
Porous metal Inorganic chemistry 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology Condensed Matter Physics 01 natural sciences 0104 chemical sciences chemistry.chemical_compound Adsorption Hydrocarbon chemistry Mechanics of Materials General Materials Science 0210 nano-technology Selectivity Porosity High iodine Benzoic acid |
| Zdroj: | Microporous and Mesoporous Materials. 305:110306 |
| ISSN: | 1387-1811 |
| DOI: | 10.1016/j.micromeso.2020.110306 |
| Popis: | In this work, a new amino-decorated porous metal-organic framework [Ni(NH2-pba)2]·2H2O·2DMF (NH2-Hpba = 3-amino-4-(pyridin-4-yl)benzoic acid) (1) has been synthesized and structurally characterized. This compound exhibits a class IIIa interpenetration of dia net with a [2 + 2] mode. For its high porosity and amino-decorated channel, this compound shows efficient CO2/N2, C2H4/CH4 and C2H2/CH4 selectivity and high iodine adsorption. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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