Ferromagnetic Behavior of an Uncommon Trinuclearcopper(II) Coordination Polymer Based on Tartarate and 1,2-bis(4-Pyridyl)ethane Linker
| Autor: | H. D. Zeng, J. X. Zhang, Y. Y. Wang, E. H. Zhou, M. M. Luo, J. Q. Liu, H. R. Zhong, B. H. Li, Jun-Cheng Jin |
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| Rok vydání: | 2018 |
| Předmět: |
010405 organic chemistry
Coordination polymer General Chemical Engineering General Chemistry Tartrate 010402 general chemistry 01 natural sciences 0104 chemical sciences Metal chemistry.chemical_compound Crystallography chemistry visual_art Tartaric acid visual_art.visual_art_medium Cluster (physics) Molecule Thermal analysis Linker |
| Zdroj: | Russian Journal of Coordination Chemistry. 44:432-438 |
| ISSN: | 1608-3318 1070-3284 |
| DOI: | 10.1134/s1070328418070072 |
| Popis: | A new Cu(II) based metal-organic framework (MOF) having formula [Cu3(H2Tar)(Tar)-(H2O)(Bpa)] · 3H2O (I) (H4Tar = tartaric acid, Bpa = 1,2-bis(4-pyridyl)ethane) has been characterized by elemental analysis, FT-IR spectra, thermal analysis, and single-crystal X-ray diffraction (CIF file CCDC no. 1575136). In I, the Cu(II) center are connected by four symmetry-related tartrate ligands into a 2D layer encapsulating trinuclear cluster, which are further bridged by Bpa molecules into a 3D framework. Complex I exhibits strong ferromagnetic behavior between metal centers. |
| Databáze: | OpenAIRE |
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