The discovery of two kinds of ion pairs
| Autor: | Johannes Smid |
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| Rok vydání: | 2004 |
| Předmět: | |
| Zdroj: | Journal of Polymer Science Part A: Polymer Chemistry. 42:3655-3667 |
| ISSN: | 1099-0518 0887-624X |
| DOI: | 10.1002/pola.20260 |
| Popis: | The discovery and implications of the existence of two kinds of ion pairs in solutions of carbanion salts is described. Also discussed are the factors controlling tight–loose ion pair equilibrium: the nature of the carbanion and its counterion, temperature, pressure, solvent, and cation-complexing additives. A few examples are presented of the effect of these ionic species on the mechanisms of anionic polymerization and proton transfer. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 3655–3667, 2004 |
| Databáze: | OpenAIRE |
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