Synthesis of monodispersed micaceous iron oxide by the oxidation of iron with oxygen under hydrothermal conditions

Autor: Satoshi Uchida, Tsugio Sato, Akitsugu Okuwaki
Rok vydání: 2007
Předmět:
Zdroj: Journal of Chemical Technology & Biotechnology. 57:221-227
ISSN: 1097-4660
0268-2575
DOI: 10.1002/jctb.280570305
Popis: The oxidation behavior of iron powder with oxygen was investigated in 5-25 m NaOH solutions at 5 MPa of oxygen partial pressure and 130-290 o C, where m=mol(kg H 2 O) -1 . Monodispersed micaceous iron oxide, α-Fe 2 O 3 , was synthesized by the oxidation of iron powder with 5 MPa of oxygen in 10-16 m NaOH solutions at 250-270 o C. The diameter of micaceous iron oxide greatly changed depending on the reaction conditions such as the temperature, reaction time and concentrations of NaOH and coexisting ions.
Databáze: OpenAIRE