Synthesis and absolute stereostructure of dinaphth[2,1- c: 1′,2′-e]oxepin-3-(5H)-one
Autor: | Gerhard Bringmann, Hans Burzlaff, Thomas Hartung, Oliver Kröcher, Joachim Lange, Klaus-Peter Gulden |
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Rok vydání: | 1994 |
Předmět: | |
Zdroj: | Tetrahedron. 50:2831-2840 |
ISSN: | 0040-4020 |
DOI: | 10.1016/s0040-4020(01)86996-9 |
Popis: | The synthesis, enantiomer analysis, and configurational assignment of dinaphth[2,1-c: 1′,2′-e]oxepin-3-(5H)-one, a seven-membered lactone-bridged chiral binaphthalene, is reported. The elucidation of the absolute configuration has been performed, independently by multiple scattering X-ray experiments and by circular dichroism (CD). |
Databáze: | OpenAIRE |
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