Synthesis of Analogues of the Antitumor (1→6)-Branched (1→3)-Glucohexaose

Autor:	Youlin Zeng, Jianjun Zhang, Fanzuo Kong
Rok vydání:	2010
Předmět:	chemistry.chemical_classification Coupling (electronics) chemistry Stereochemistry General Chemistry Trisaccharide Oligosaccharide Acceptor
Zdroj:	Chinese Journal of Chemistry. 22:460-466
ISSN:	1001-604X
DOI:	10.1002/cjoc.20040220514
Popis:	β-D-Glcp( 13)-[β-D-Glcp-( 16)-/α-D-Manp-( 13)-β-D-Glcp( 13)-[β-D-Glcp-(16)-]D-Glcp (18) and β-D-Glcp( 13)-[β-D-Glcp-( 16)-] α-D-Manp-( 13)-β-D-Glcp-( 1 3)-[β-D-Glcp-( 16)-]β-D-Glcp-D-(13)-Glcp-1OMe (29) were synthesized as the analogues of the immunomodulator β-D-Glcp-(13)-[β-D-Glcp-(16)-]α-D-Glcp-(13)-β-D-Glcp-(13)-(β-D-Glcp-(16)-]D-Glcp through coupling of trisaccharide donors 9 with trisaccharide acceptor 16 and terrasaccharide acceptor 27 followed by deprotection. respectively.
Databáze:	OpenAIRE
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