New redox deposition-precipitation method for preparation of supported manganese oxide catalysts
Autor: | Izaskun Barrio, Iñigo Legorburu, José Antonio Odriozola, M.I. Domínguez, Miguel Ángel Centeno, Mario Montes |
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Rok vydání: | 2005 |
Předmět: | |
Zdroj: | Catalysis Letters. 101:151-157 |
ISSN: | 1572-879X 1011-372X |
DOI: | 10.1007/s10562-005-4882-6 |
Popis: | A new preparation method has been developed to produce homogeneous coatings of manganese compounds on alumina-coated monoliths by redox deposition-precipitation using acetone as solvent. The deposition is produced by reduction of manganese permanganate with ethanol. The Lewis acid sites on the alumina catalyze this reaction. Thus, the precipitation is produced preferentially on the surface of the monolith and not in the bulk of the solution. Monoliths prepared by this method are very active for the complete oxidation of oxygenated volatile organic compounds (VOCs). These monoliths consist of a mixture of complex phases including aluminum, sulfated alumina, potassium sulfate and manganese oxide. |
Databáze: | OpenAIRE |
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