Kinetics and mechanism of reaction between polyfluorinated alcohols and thionyl chloride

Autor:	A. I. Rakhimov, V. M. Volchkov, Yu. V. Popov, E. A. Zauer, O. V. Vostrikova
Rok vydání:	2004
Předmět:	Isothermal microcalorimetry Chemical kinetics chemistry.chemical_compound Thionyl chloride chemistry Organic Chemistry Inorganic chemistry Kinetics Nucleophilic substitution Chlorine chemistry.chemical_element Nuclear magnetic resonance spectroscopy Triethylamine
Zdroj:	Russian Journal of Organic Chemistry. 40:1579-1582
ISSN:	1608-3393 1070-4280
Popis:	Complexing of polyfluorinated alcohols with triethylamine was studied by means of microcalorimetry, IR and NMR spectroscopy. The reaction kinetics of these polar complexes with thionyl chloride was investigated using calorimetry of heat fluxes applying mathematical simulation procedure. The second order of nucleophilic substitution reaction of chlorine by polyfluoroalkoxy group was established.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::e74af90728b0ee56c22a4f6d1b02b45f https://doi.org/10.1007/s11178-005-0063-8 Zobrazit plný text záznamu Plný text ve formátu PDF