Unique bonding and geometry in .eta.-cyclopentadienyltantalum-diene complexes. Preparation, x-ray structural analyses, and EHMO calculations
| Autor: | Akira Nakamura, Takuji Okamoto, Keonil Lee, Kazuyuki Tatsumi, Hajime Yasuda, Yasushi Kai, Nobutami Kasai, Kazushi Mashima, Noriko Kanehisa |
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| Rok vydání: | 1985 |
| Předmět: |
chemistry.chemical_classification
Diene Stereochemistry X-ray General Chemistry Nuclear magnetic resonance spectroscopy Crystal structure Biochemistry Extended Hückel method Catalysis chemistry.chemical_compound Crystallography Colloid and Surface Chemistry chemistry X-ray crystallography Molecule Inorganic compound |
| Zdroj: | Journal of the American Chemical Society. 107:2410-2422 |
| ISSN: | 1520-5126 0002-7863 |
| DOI: | 10.1021/ja00294a036 |
| Popis: | Preparation et caracterisation par spectre de masse, RMN et diffraction RX de six complexes CpTaCl 2 (diene) et Cp*TaCl 2 (diene) avec Cp=cyclopentadienyl et Cp*=pentamethylcyclopentadienyl. Calcul par la methode de Huckel generalisee |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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