Alkylation by Polyprenols of ortho- and para-Cresols: Synthesis of Isomeric Polyprenylcresols

Autor:	U. T. Zokirova, Kh. M. Shakhidoyatov, A. V. Kuchin, N. K. Khidirova, A. A. Koroleva, B. Zh. Elmuradov
Rok vydání:	2020
Předmět:	Reaction conditions 010405 organic chemistry Plant Science General Chemistry Alkylation 01 natural sciences General Biochemistry Genetics and Molecular Biology 0104 chemical sciences 010404 medicinal & biomolecular chemistry Polyprenol chemistry.chemical_compound chemistry Polymerization Reagent parasitic diseases Organic chemistry
Zdroj:	Chemistry of Natural Compounds. 56:39-43
ISSN:	1573-8388 0009-3130
Popis:	Alkylation by polyprenols of o- and p-cresols in the presence of equimolar amounts of the corresponding aluminum cresolates occurred regioselectively to form o-alkyl products regardless of the ratio of starting reagents. Production of 2,6-dipolyprenyl-4-methylphenol was favored if an excess of polyprenols was used with aluminum p-cresolate. A significant amount of polyprenol polymerization products was obtained under the studied reaction conditions.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::e6ac71c4d11889b89e5a798fc390eb3d https://doi.org/10.1007/s10600-020-02939-x Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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