Characterization of Monohalogen and Monopseudohalogen Derivatives of Dimethylgermane

Autor:	John E. Drake, Raymond T. Hemmings, Geoffrey K. Barker
Rok vydání:	1974
Předmět:	Chemistry Computational chemistry Yield (chemistry) Organic Chemistry General Chemistry Catalysis Characterization (materials science)
Zdroj:	Canadian Journal of Chemistry. 52:2622-2633
ISSN:	1480-3291 0008-4042
DOI:	10.1139/v74-383
Popis:	The high yield syntheses of Me2GeHX (X = F, Cl, Br, I) and Me2GeHPs (Ps = CN, N3, NCO, NCS, OAc) are reported. The dimethylgermane derivatives are identified and characterized by various physical methods and by cleavage reactions where appropriate. A normal coordinate analysis based on a modified valence force field provides confirmation of the assignments for all the fundamental frequencies, except the torsional modes, in the vibrational spectra of the monohalogeno(dimethyl)germanes, Me2GeHX.
Databáze:	OpenAIRE
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