Framework Isomerism in a Series of btb-Containing In-Derived Metal–Organic Frameworks

Autor:	Jeremy I. Feldblyum, Sarah E. Springer, Naseem Amirmokhtari, Douglas T. Genna, Audrey B. Crom, Joseph J. Mihaly, Matthias Zeller
Rok vydání:	2019
Předmět:	Secondary building unit Series (mathematics) 010405 organic chemistry Chemistry General Chemistry 010402 general chemistry Condensed Matter Physics 01 natural sciences 0104 chemical sciences Computational chemistry Yield (chemistry) Halogen General Materials Science Metal-organic framework
Zdroj:	Crystal Growth & Design. 19:3124-3129
ISSN:	1528-7505 1528-7483
DOI:	10.1021/acs.cgd.9b00611
Popis:	The discovery of new inorganic building units for metal–organic framework (MOF) synthesis remains challenging. We hypothesized that incorporation of X-type halogen capping ligands on indium-building units would yield a series of previously unknown frameworks and the placement of the halogen could lead to framework isomerism. Herein we report the synthesis of three new MOFs; two (YCM-31 and YCM-32) contain an [In(CO2R)3Cl]− secondary building unit (SBU) and are framework isomers of each other. A third new MOF, ZJU-28′, contains an [In(CO2R)4]− SBU and is a framework isomer of the known MOF ZJU-28. The conditions to control the syntheses of these isomers through ammonium-cation templation, along with the rationale for their formation are discussed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::e55f7f512055c5654cc73d8268d579f6 https://doi.org/10.1021/acs.cgd.9b00611 Zobrazit plný text záznamu