Adsorption of methane + ethane and methane + carbon monoxide on molecular sieves

Autor: Christian Clavaud, Marie-Claude Veyssiere, Pierre Cartraud, Andre Cointot
Rok vydání: 1981
Předmět:
Zdroj: Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases. 77:1417
ISSN: 0300-9599
Popis: Experimental sorption isotherms are obtained for methane, ethane and carbon monoxide in three molecular sieves (two zeolitic and one carbon). Pressures from a few millibar absolute to as high as 30 bar are covered. Sorption isotherms for the binary mixtures methane + ethane and methane + carbon monoxide in the same sorbents are also obtained at 298 K and at equilibrium pressures within the range 2–12 bar. A circulating volumetric apparatus was built and employed for all the binary mixture sorption investigations. Total adsorbed amounts are determined for different gas-phase compositions. Vapour–adsorbate equilibria are determined. A correlation based on I.A.S.T. (Ideal Adsorbed Solution Theory) was studied in order to predict the vapour–adsorbate equilibria.
Databáze: OpenAIRE